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朱贤青

职称:副教授

联系方式:xianqingzhu@cqu.edu.cn

主要从事:主要从事生物质热化学预处理及高值化利用、城乡固体废弃物的热解气化技术及其CFD模拟以及废弃锂电池热化学回收等方面的教学与科研工作。
  • 个人简介
  • 教育经历
  • 研究方向
  • 本科生及研究生培养
  • 科研项目
  • 代表性论文

朱贤青,博士,副教授。长期从事于生物质基储能电极材料(超级电容器、钠离子电池硬碳负极)、生物质热解/水热转化制取高值化学品、废旧锂电池热化学回收等方面的相关研究工作。作为项目负责人主持国家自然科学基金、重庆市自然科学基金面上项目、中国博士后科学基金面上项目等项目8项,主研国家自然科学基金重点项目1项(排名第三)、重庆市技术创新与应用发展重点项目1项(排名第二),作为主要研究人员参与国家自然科学基金国际合作项目、面上项目多项。为国家自然科学基金委创新群体和科技部重点领域创新团队的骨干成员,受聘为中国化工学会工程热化学专委会青年委员中国能源学会专家委员会新能源专家委员会委员、广东高校科技成果转化专家组专家、教育部学位与研究生教育发展中心硕士学位论文评审专家,担任中科院1区期刊International Journal of Coal Science and Technology的青年编委、担任Frontiers in Energy Research期刊副主编(Q2)。在Applied Energy、Journal of Hazardous Materials、Fuel、Chemical Engineering Journal、Bioresource Technology等国际权威SCI期刊上发表论文60余篇。申请国家发明专利20余项,已授权10余项。参加国内外学术会议20余次,并在国内外学术会议上做邀请/口头报告10余次。担任Fuel、Energy、ACS Sustainable Chemistry & Engineering等20余个国际权威期刊审稿人。


2013/09-2018/06     华中科技大学   煤燃烧国家重点实验室   博士

2009/09-2013/06     华中科技大学   能源与动力工程学院     学士


[1] 生物质基储能电极材料(超级电容器、钠离子电池硬碳负极)

[2] 电解水制氢、生物质热解/水热转化制取高值化学品

[3] 废旧锂电池热化学回收及高效热催化剂/电催化剂构筑


研究生培养:

欢迎认真踏实、对以上研究方向有兴趣的同学报考研究生!向优秀本科生提供助研、节能减排等科研项目训练机会,欢迎随时联系与交流!


科研项目:

[1] 国家自然科学基金青年基金项目,2020-2022,主持

[2] 重庆市技术创新与应用发展重点项目,2019-2022,主研(排名第二)

[3] 重庆市自然科学基金面上项目,2023-2026,主持

[4] 国家自然科学基金重点项目,2023-2027,主研(排名第三)

[5] 中国博士后科学基金面上项目,2022-2023,主持

[6] 高校教师特色创新研究项目,2022-2023,主持

[7] 低品位能源利用技术及系统教育部重点实验室开放基金,2022-2023,主持

[8] 煤炭高效利用与绿色化工国家重点实验室开放基金,2022-2023,主持

[9] 中央高校基本科研业务费,2019-2020,主持

[10] 重庆大学引进人才科研启动费,2018-至今,主持

 


代表性论文:

[1] Mian Xu, Xianqing Zhu*, Yiming Lai, et al. Production of hierarchical porous biocarbon based on deep eutectic solvent fractionated lignin nanoparticles for high-performance supercapacitor. Applied Energy, 2024, 353,122095.

[2] Mian Xu, Zhongyue Zhou, Xianqing Zhu*, Qiang Liao*, et al. Insight into the enhancement mechanism of levoglucosan production from biomass pyrolysis by deep eutectic solvent fractionation. Proceedings of the Combustion Institute, 2024.oral report

[3] Qian Shen, Xianqing Zhu*, Yang Peng, Qiang Liao, et al. Structure evolution characteristic of hydrochar and nitrogentransformation mechanism during co-hydrothermal carbonization process of microalgae and biomass. Energy, 2024, 295, 131028.

[4] Mian Xu, Zhipeng Shi, Xianqing Zhu*, Yiming Lai, Qiang Liao, et al. Ex-situ catalytic upgrading of biomass pyrolysis volatiles over thermal-decomposition products of spent lithium-ion batteries for bio-oil deoxygenation and hydrogen-rich syngas production. International Journal of Hydrogen Energy, 2024, 52:83-96.

[5] Yiming Lai, Xianqing Zhu*, Jun Li*, Qiang Liao, et al. Recycling of spent LiFePO4 batteries by oxidizing roasting: Kinetic analysis and thermal conversion mechanism. Journal of Environmental Chemical Engineering, 2023, 11:110799.

[6] Yiming Lai, Xianqing Zhu*, Jun Li, et al. Recovery and regeneration of anode graphite from spent lithium-ion batteries through deep eutectic solvent treatment: Structural characteristics, electrochemical performance and regeneration mechanism. Chemical Engineering Journal, 2023, 457: 141196.

[7] Xianqing Zhu, Man Liu, Qintao Sun, et al. Elucidation of the interaction effects of cellulose, hemicellulose and lignin during degradative solvent extraction of lignocellulosic biomass. Fuel, 2022, 327: 125141.

[8] Xianqing Zhu, Zhipeng Shi, Xun Zhu, et al. Catalytic pyrolysis of biomass with thermal treatment products of spent lithium-ion batteries for the upgrading of bio-oil and syngas. Fuel, 2022, 326: 125018. 

[9]  Yiming Lai, Xianqing Zhu*, Jun Li, et al.. Efficient recovery of valuable metals from cathode materials of spent LiCoO2 batteries via co-pyrolysis with cheap carbonaceous materials. Waste Management, 2022, 14812-21.  

[10] Mian Xu, Xianqing Zhu*, Xian Li, Zhenzhong Hu, Yun Huang, Ao Xia, Hong Yao. Investigation of the combustion behaviors and kinetic modelling of municipal solid waste char under isothermal conditions using a micro-fluidized bed. Journal of Environmental Chemical Engineering, 2021, 9: 105984.

[11] Qin Peng, Xianqing Zhu*, Jun Li*, Qiang Liao, Yiming Lai, Liang Zhang, Qian Fu, Xun Zhu. A novel method for carbon removal and valuable metal recovery by incorporating steam into the reduction-roasting process of spent lithium-ion batteries. Waste Management, 2021, 134: 100-109.

[12] Xiaobo Guo, Huize Chen, Xianqing Zhu*, Ao Xia*, Qiang Liao, Yun Huang, Xun Zhu. Revealing the role of conductive materials on facilitating direct interspecies electron transfer in syntrophic methanogenesis: A thermodynamic analysis. Energy, 2021, 229: 120747.

[13] Dong Feng, Ao Xia*, Yun Huang, Xianqing Zhu, Xun Zhu, Qiang Liao. Effects of carbon cloth on anaerobic digestion of high concentration organic wastewater under various mixing conditions. Journal of Hazardous Materials, 2022, 423: 127100.

[14] Yunheng Tang, Yun Huang, Wentian Gan, Ao Xia, Qiang Liao, Xianqing Zhu. Ethanol production from gas fermentation: Rapid enrichment and domestication of bacterial community with continuous CO/CO2 gas. Renewable Energy, 2021, 175: 337-344.

[15] Weida Zeng, Yun Huang*, Ao Xia, Qiang Liao, Keming Chen, Xun Zhu, Xianqing Zhu. Thermoresponsive Surfaces Grafted by Shrinkable Hydrogel Poly(N-isopropylacrylamide) for Controlling Microalgae Cells Adhesion during Biofilm Cultivation. Environmental Science and Technology, 2021, 55, 2, 1178–1189.

[16] Jingwei Fu, Yun Huang, Qiang Liao*, Xun Zhu, Ao Xia, Xianqing Zhu, Jo-Shu Chang. Boosting photo-biochemical conversion and carbon dioxide bio-fixation of Chlorella vulgaris in an optimized photobioreactor with airfoil-shaped deflectors. Bioresource Technology, 2021, 337: 125355.

[17] Cheng Chen, Chihe Sun, Ao Xia*, Qiang Liao, Xiaobo Guo, Yun Huang, Qian Fu, Xianqing Zhu, Xun Zhu. Sustainable biohythane production from algal bloom biomass through two-stage fermentation: Impacts of the physicochemical characteristics and fermentation performance. International Journal of Hydrogen Energy, 2020, 45: 344 61-34472.

[18] Dong Feng, Ao Xia*, Qiang Liao, Abdul-Sattar Nizami, Chihe Sun, Yun Huang, Xianqing Zhu, Xun Zhu. Carbon cloth facilitates semi-continuous anaerobic digestion of organic wastewater rich in volatile fatty acids from dark fermentation. Environmental Pollution, 2021, 272: 116030.

[19] Jun Li, Yiming Lai, Xianqing Zhu*, Qiang Liao, Ao Xia, Yun Huang, Xun Zhu. Pyrolysis kinetics and reaction mechanism of the electrode materials during the spent LiCoO2 batteries recovery process. Journal of Hazardous Materials, 2020, 398, 122955.

[20] Man Liu, Xianqing Zhu*, Rong Chen*, Qiang Liao, Ao Xia, Yun Huang. Influence of torrefaction, hydrothermal carbonization and degradative solvent extraction pretreatments on moisture absorption and self-ignition characteristics of biomass. Fuel, 2020, 282, 118843.

[21] Xianqing Zhu, Weixiang Qian, Xian Li, Shan Tong, Zhenzhong Hu, Yun Huang, Ao Xia, Hong Yao. Moisture adsorption and spontaneous combustion characteristics of biomass wastes after degradative solvent extraction. Fuel, 2020, 266, 117109.

[22] Xiaobo Guo, Chihe Sun, Richen Lin, Ao Xia, Yun Huang, Xianqing Zhu, Pau-Loke Show, Jerry D.Murphy. Effects of foam nickel supplementation on anaerobic digestion: Direct interspecies electron transfer. Journal of Hazardous Materials, 2020, 399, 122830.

[23] Weixiang Qian, Xian Li, Xianqing Zhu, Zhenzhong Hu, Xu Zhang, Guangqian Luo and  Hong Yao. Preparation of activated carbon nanofibers using degradative solvent extraction products obtained from low-rank coal and their utilization in supercapacitors. RSC Advances, 2020, 10(14): 8172-8180.

[24] Chihe Sun, Qiang Liao, Ao Xia, Qian Fu, Yun Huang, Xianqing Zhu, Xun Zhu, Zhengxin Wang. Degradation and transformation of furfural derivatives from hydrothermal pre-treated algae and lignocellulosic biomass during hydrogen fermentation. Renewable and Sustainable Energy Reviews, 2020, 131,109983.

[25] Wei Chaoyang, HuangYun, Liao Qiang, Xia Ao, Zhu Xun, Zhu Xianqing. Analysis of the energy barrier between Chlorella vulgaris cells and their interfacial interactions with cationic starch under different pH and ionic strength. Bioresource Technology, 2020, 304,123012.

[26] Wei Chaoyang, Huang Yun, Liao Qiang, Zhu Xun, Xia Ao, Zhu Xianqing. Application of bubble carrying to Chlorella vulgaris flocculation with branched cationic starch: An efficient and economical harvesting method for biofuel production. Energy Conversion and Management, 2020, 213, 112833.

[27] Wu Chao, Qian Weixiang, Li Xian, Zhu Xianqinget al. Preparation of carbon nanofber with specifc features by degradative solvent extraction product from biomass wastes. Fuel, 2019, 258:116149.  

[28] Dacres Omar D., Tong Shan, Li Xian, Zhu Xianqinget al. Pyrolysis kinetics of biomasses pretreated by gas-pressurized torrefaction. Energy Conversion and Management, 2019, 182:117-125.

[29] Yun Huang, Chaoyang Wei, Qiang Liao, Ao Xia, Xun Zhu, Xianqing Zhu, Zhu Xianqinget al. Biodegradable branched cationic starch with high C/N ratio for Chlorella vulgaris cells concentration: Regulating microalgae flocculation performance by pH. Bioresource Technology, 2019, 276: 133-139.

[30] Deng Zhichao, Xia Ao, Liao Qiang, Zhu Xianqinget al. Laccase pretreatment of wheat straw: effects of the physicochemical characteristics and the kinetics of enzymatic hydrolysis. Biotechnology for Biofuels, 2019, 12:159.

[31] Wei Chaoyang, Huang Yun, Liao Qiang, Xia Ao, Zhu Xun, Zhu Xianqing. Adsorption thermodynamic characteristics of Chlorella vulgaris with organic polymer adsorbent cationic starch: Effect of temperature on adsorption capacity and rate. Bioresource Technology, 2019, 2019, 293:122056.

[32] Ding Lizhi, Gao Yaxin, Li Xian, Wang Wenhui, Xue Yi, Zhu Xianqinget al. A novel CO2-water leaching method for AAEM removal from Zhundong coal. Fuel, 2019, 237:786-792.

[33] Jian Yiming, Li Xian, Zhu Xianqing, Ashida Ryuichi, et al. Interaction between low-rank coal and biomass during degradative solvent extraction. Journal of Fuel Chemistry and Technology, 2019, 47:14-22.

[34] Zhu Xianqing, Tong Shan, Li Xian, et al. Conversion of Biomass into High-Quality Bio-oils by Degradative Solvent Extraction Combined with Subsequent Pyrolysis. Energy & Fuels, 2017, 31(4): 3987-3994.

[35] Zhu Xianqing, Tang Jian, Li Xian, et al. Modeling and Kinetic Study of Degradative Solvent Extraction of Biomass Wastes. Energy & Fuels, 2017, 31(5): 5097-5103.

[36] Zhu Xianqing, Li Xian, Xiao Li, et al. Novel carbon-rich additives preparation by degradative solvent extraction of biomass wastes for coke-making. Bioresource Technology, 2016, 207: 85-91.

[37] Zhu Xianqing, Xue Yi, Li Xian, et al. Mechanism study of degradative solvent extraction of biomass. Fuel, 2016, 165: 10-18.

[38] Zhu Xianqing, Zhang Zong, Zhou Qixiong, et al. Upgrading and multistage separation of rice straw by degradative solvent extraction. Journal of Fuel Chemistry and Technology, 2015, 43(04): 422-428

[39] Xiao Li, Zhu Xianqing, Li Xian, et al. Effect of Pressurized Torrefaction Pretreatments on Biomass CO2 Gasification. Energy & Fuels, 2015, 29(11): 7309-7316.

[40] Li Xian*, Zhu Xianqing, Kenshiro Okuda, et al. Preparation of carbon fibers from low-molecular-weight compounds obtained from low-rank coal and biomass by solvent extraction. New Carbon Materials, 2017, 32(1): 41-47.

[41] Tong Shan, Xiao Li, Li Xian, Zhu Xianqing, et al. A gas-pressurized torrefaction method for biomass wastes. Energy Conversion and Management, 2018, 173: 29-36.

[42] Li Xian, Zhang Zong, Zhang Lei, Zhu Xianqing, et al. Degradative solvent extraction of low-rank coals by the mixture of low molecular weight extract and solvent as recycled solvent. Fuel Processing Technology, 2018,173: 48-55

[34] Xu Kai, Dong Jizhou, Hu Hongyun, Zhu Xianqing, et al. Effect of ash components on the performance of solid oxide electrolyte-based carbon fuel cells. Energy & Fuels, 2018, 32(4): 4538-4546.

[43] Xu Yang, Zeng Xiaobo, Zhang Bi, Zhu Xianqing, et al. Experiment and Kinetic Study of Elemental Mercury Adsorption over a Novel Chlorinated Sorbent Derived from Coal and Waste Polyvinyl Chloride. Energy & Fuels, 2016, 30(12): 10635-10642. 

[44] Xu Kai, Hu Hongyun, Li Zehua, Zhu Xianqinget al. Investigation of the anode reactions in solid oxide electrolyte based carbon fuel cells. International Journal of Hydrogen Energy, 2017, 42(15): 10264-10274.

[45] Gao Yaxin, Ding Lizhi, Li Xian, Wang Wenhui, Xue Yi, Zhu Xianqing, et al. Na&Ca removal from Zhundong coal by a novel CO2-water leaching method and the ashing behavior of the leached coal. Fuel, 2017, 210: 8-14.

[46] Li Xian, Wu Zhengyu, Zhang Lian, Liu Xiaowei, Zhu Xianqing, et al. An updated acid dew point temperature estimation method for air-firing and oxy-fuel combustion processes. Fuel Processing Technology, 2016, 154: 204-209.

[47] Fang Yuan, Zou Renjie, Luo Guangqian, Chen Juan, Li Zehua, Mao Zhengjiang, Zhu Xianqing, et al. Kinetic Study on Coal Char Combustion in a Microfluidized Bed. Energy & Fuels, 2017, 31:3243-52.

[48] Li Xian, Zhu Xianqing, Xiao Li, et al. Degradative solvent extraction of demineralized and ion-exchanged low-rank coals. Journal of Fuel Chemistry and Technology, 2014, 42(8): 897-904.

[49] 朱贤青,张宗,周岐雄,等. 稻杆的热溶剂提质及多级分离. 燃料化学学报. 2015, 43(04): 422-428.

 

发明专利(仅列15项)

1. 朱贤青,施志鹏,朱恂,廖强,李俊,夏奡,黄云. 一种利用废旧锂电池热处理产物催化生物质热解的方法,2021-1-202041-1-20,中国,ZL202110073016.5

2. 朱贤青,赖一铭,李俊,廖强,张亮,付乾,朱恂. 利用热解焦高效干法回收废旧锂电池的方法,2021-7-16,中国,202110803934.9

3. 朱贤青,廖强,朱恂,王岩,夏奡,黄云. 一种废旧锂电池基金属改性催化剂催化生物质热解的方法,2022-10-11,中国,CN202211240657.6.

4. 朱贤青,廖强,李俊,赖一铭,朱恂,付乾,张亮. 一种利用低共熔溶剂处理废旧石墨直接再生的方法,2022-06-22,中国,CN202210710725.4.

5. 廖强,朱贤青,朱恂,夏奡,黄云. 一种利用废旧锂电池热处理产物异位催化生物质热解的方法,2022-10-11,中国,CN202211241012.4. 

6. 李俊,彭琴,朱贤青,付乾,张亮,朱恂,廖强. 一种利用水蒸气高效还原回收废旧锂电池的处置方法. 国家发明专利. 专利号:202010677996.5

7. 廖强,黄云,夏奡,付乾,李俊,朱恂,朱贤青. 太阳能驱动生化热化学转化制取微藻燃料方法及系统. 国家发明专利. 专利号:2019108273654

8. 黄云,郑亚萍,廖强,夏奡,付乾,李俊,朱恂,朱贤青. 基于pH调节的微藻生物膜的快速接种方法. 国家发明专利. 专利号:2019100814089

9. 李显,胡振中,涂正俊,朱贤青,吴超,聂帅,徐凯,姚洪. 一种具有高比表面积的活性炭及其制备方法. 国家发明专利. 专利号:2019100684583

10. 李显,熊钊,丁立志,高亚新,朱贤青,姚洪,徐凯. 一种生物质的脱灰方法. 国家发明专利. 专利号:2018109231584

11. 朱贤青,李显,姚洪,徐凯等. 一种用低阶煤热溶萃取残渣制备高品质活性炭的方法. 国家发明专利,专利号:201710725953.8

12. 朱贤青,李显,姚洪,徐凯等. 一种耦合热溶萃取和热解制备高品质生物油和气体的方法. 国家发明专利,已授权:ZL201610834375.7

13. 朱贤青,李显,姚洪,胡振中等. 一种低阶煤热溶剂萃取提质方法,国家发明专利,专利号:201710769336.8

14. 李显,朱贤青,姚洪,刘华强等. 一种气煤及其制备方法. 国家发明专利,已授权:ZL201610035651.3

15. 李显,朱贤青,李宇航等. 一种将生物质萃取产物作为添加剂应用于配煤炼焦的方法. 国家发明专利,已授权:ZL201510081203.2


 

学术会议交流:

1.     Chuanchang Xu, Xianqing Zhu*, Jun Li*, Yiming Lai, Ao Xia, Yun Huang, Xun Zhu, Qiang Liao. Simulation of Co-gasification of Sawdust and Polyethylene in an Updraft Fixed Bed gasifier for Production of Hydrogen-rich Syngas. 13th International Conference on Applied Energy. November 29-December 2, 2021

2.     Zhipeng Shi, Xianqing Zhu*, Xun Zhu*, Mian Xu, Ao Xia, Yun Huang, Qiang Liao. Catalytic Pyrolysis of Biomass to Produce High-grade Bio-oil and Syngas with Thermal Treatment Products of Spent Lithium-ion Batteries. 24th Conference on Process Integration, Modelling and Optimisation for Energy Saving and Pollution Reduction, October 31-November 3, 2021, Brno, CZ

3.     Man Liu, Xianqing Zhu*, Rong Chen, Qiang Liao, Yun Huang, Ao Xia, Xun Zhu. Effect of torrefaction, hydrothermal carbonization and degradative solvent extraction on moisture adsorption and spontaneous combustion characteristics of biomass. The 14th Asian Biohydrogen, Biorefinery and Bioprocess Symposium. November 13-15, 2019 Hanoi, Vietnam.

4.     Xianqing Zhu, Shan Tong, Xian Li, et al. Conversion of biomass into high-quality products by degradative solvent extraction combined with subsequent pyrolysis. 6th International Conference on Sustainable Energy and Environment. November 28-30, 2017, Bangkok, Thailand. (oral report)

5.     Xianqing Zhu, Jin Ge, Shan Tong, et al. Novel additives obtained from low grade biomasses for coke-making. 18th International Coal Preparation Congress. June 28-30, 2016, Saint Petersburg, Russia. (oral report)

6.     Xianqing Zhu, Shiping Huang, Huaqiang Liu, et al. Coke-making additives preparation by degradative solvent extraction of biomass wastes. 13th China-Japan Symposium on Coal and C1 Chemistry. September 1-3, 2015, Dunhuang, China. (oral report)

7.     Yi Xue, Wenhui Wang, Xianqing Zhu, et al. Removal of Na&Ca from zhundong coal by CO2-water treatment. 13th China-Japan Symposium on Coal and C1 Chemistry. September 1-3, 2015, Dunhuang, China.

8.     Zong Zhang, Yi Xue, Xianqing Zhu, Xian Li, et al. Combustion Behavior of Low-Rank Coal Upgraded by Degradative Solvent Extraction. Clean Coal Technology and Sustainable Development, Springer, 2016, 31-37.

9.     Zehua Li, Kai Xu, Yuan Fang, Xianqing Zhu, et al. Effect of CO2 and steam gasification on char combustion in an O2/CO2/Steam atmosphere. 5th International Symposium on Gasification and Its Application. November 28-30, 2016, Busan, Korea.

10.  Xian Li, Zong Zhang, Lei Zhang, Xianqing Zhu, et al. Degradative solvent extraction of low-rank coals by the mixture of low molecular weight extract and solvent as recycled solvent. 6th Sino-Australian Symposium on Advanced Coal and Biomass Utilisation Technologies. December 4-8, 2017, Perth, Western Australia. (oral report)